Atmospheric CO2 concentrations have reached significant levels during the industrial era, necessitating the implementation of effective carbon dioxide removal (CDR) technologies. Enhanced Rock Weathering (ERW) using basalt has emerged as a high-potential strategy, leveraging its mafic composition to sequester CO2 as stable carbonates. This review analyzes ERW’s geochemical processes, application methods, and multifaceted co-benefits, such as restoring “background fertility” and improving soil structure. The literature indicates that while small-scale applications range from 1.5 to 6 Mg·ha−1·yr−1, intensive agricultural rates typically reach 40–100 Mg·ha−1·yr−1. Global models estimate a sequestration potential of up to 4.9 × 109 Mg CO2·yr−1 for basalt, although field-scale results vary significantly, reaching uptake rates of up to 4 Mg CO2·ha−1 depending on pedological conditions and crop types. Despite this promise, transitioning to large-scale deployment faces critical hurdles, including operational difficulties in mechanized spreading and a scarcity of audited, long-term field data. Future research must prioritize standardized protocols and comprehensive economic analyses to bridge the gap between theoretical models and empirical evidence. Ultimately, ERW represents a multifaceted solution for climate stabilization and sustainable food security, provided that sequestration efficacy and environmental safety are rigorously verified through high-application field trials.
